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2.1 - Electric Potential Energy

Conservative Forces and Potential Energy

From mechanics, we know that every conservative force has an associated potential energy. The electric force is conservative, which means: - The work done is path-independent. - Energy is conserved. - A potential energy function exists.
So just as the gravitational force has gravitational potential energy, the electric force has electric potential energy.

Definition

Electric potential energy is the work an external force has to do to bring point charges in from an infinite distance to their current positions.
This energy belongs to the system of charges, not to either charge by itself. Two charges 0.30 m apart might store 0.30 J, but that energy is in their interaction, so it belongs to the pair. The definition also assumes the external force moves the charges slowly, starting and ending at rest, so none of its work turns into kinetic energy. All of that work gets stored as UEU_E.

Compared to Gravitational Potential Energy

Gravitational PE
Electric PE
Work against gravity
Work against the electric force
Bringing mass closer to Earth
Bringing charges into a configuration
Ug=−GMmrU_g = -\frac{GMm}{r} (off the surface)
Ue=kq1q2rU_e = k\frac{q_1q_2}{r}
Always attractive
Attractive or repulsive

The Formula

The electric potential energy between two point charges is:
U=kq1q2rU = k\frac{q_1q_2}{r}
or equivalently:
U=14πϵ0q1q2rU = \frac{1}{4\pi\epsilon_0}\frac{q_1q_2}{r}
where: - UU = electric potential energy (J) - k=9×109k = 9 \times 10^9 N·m²/C² - q1,q2q_1, q_2 = the two charges (C) - rr = distance between them (m) - ϵ0=8.85×10−12\epsilon_0 = 8.85 \times 10^{-12} C²/(N·m²)
Remember that k=14πϵ0k = \frac{1}{4\pi\epsilon_0}.

The Derivation Connection

Electric potential energy comes from integrating the electric force:
U=−∫∞rF⃗⋅dr⃗U = -\int_{\infty}^{r} \vec{F} \cdot d\vec{r}
That’s analogous to how gravitational potential energy relates to gravitational force.
Here’s where the formula comes from, using the definition above. Hold q1q_1 fixed at the origin and bring q2q_2 in from infinity to a distance rr. The electric force on q2q_2 is kq1q2r′2k\frac{q_1q_2}{r'^2} along +r^+\hat{r}. To move q2q_2 without speeding it up, the external force has to be equal and opposite, Fext=−kq1q2r′2F_{ext} = -k\frac{q_1q_2}{r'^2}. Add up its work on the way in:
Wext=∫∞rFext dr′=−kq1q2∫∞rdr′r′2=−kq1q2[−1r′]∞r=kq1q2rW_{ext} = \int_{\infty}^{r} F_{ext}\,dr' = -kq_1q_2\int_{\infty}^{r} \frac{dr'}{r'^2} = -kq_1q_2\left[-\frac{1}{r'}\right]_{\infty}^{r} = k\frac{q_1q_2}{r}
That work is exactly the stored energy, so UE=kq1q2rU_E = k\frac{q_1q_2}{r}. The sign takes care of itself: for like charges q1q2>0q_1q_2 > 0, so you do positive work pushing them together.

Example: Work to Bring Two Charges Together

Problem: A +5.0+5.0 μC charge is held fixed. (a) How much work does an external force have to do to bring a +2.0+2.0 μC charge from very far away to a point 0.30 m from it, starting and ending at rest? (b) How much more work does it take to push the +2.0+2.0 μC charge in from 0.30 m to 0.10 m?
Solution (a): Starting from infinity, Ui=0U_i = 0, so the work equals the final potential energy of the pair:
W=UE=kq1q2r=(9.0×109)(5.0×10−6)(2.0×10−6)0.30=0.30 JW = U_E = k\frac{q_1q_2}{r} = (9.0 \times 10^9)\frac{(5.0 \times 10^{-6})(2.0 \times 10^{-6})}{0.30} = 0.30 \text{ J}
Solution (b): The work is the change in potential energy:
Uf=(9.0×109)(5.0×10−6)(2.0×10−6)0.10=0.90 JU_f = (9.0 \times 10^9)\frac{(5.0 \times 10^{-6})(2.0 \times 10^{-6})}{0.10} = 0.90 \text{ J}W=Uf−Ui=0.90 J−0.30 J=0.60 JW = U_f - U_i = 0.90 \text{ J} - 0.30 \text{ J} = 0.60 \text{ J}
Answer: (a) 0.30 J. (b) 0.60 J more. Since UE∝1rU_E \propto \frac{1}{r}, cutting the distance to a third triples UEU_E (from 0.30 J to 0.90 J). If the moving charge were −2.0-2.0 μC instead, UEU_E at 0.30 m would be −0.30-0.30 J, so the external force would do negative work: it has to hold the charge back as the attraction pulls it in.

The Sign of Electric Potential Energy

The sign depends on whether the charges attract or repel. This is one of the most important things to get right.

Same Sign Charges (Both + or Both −)

The charges want to separate, since likes repel.
2.1 - Electric Potential Energy
Characteristics: - U>0U > 0, positive potential energy. - UU increases as the charges get closer. - UU decreases as the charges get farther apart. - The force points toward decreasing UU, so away from each other.
Example: two protons pushed close together store positive PE.

Opposite Sign Charges (+ and −)

The charges want to come together, since opposites attract.
2.1 - Electric Potential Energy
Characteristics: - U<0U < 0, negative potential energy. - UU decreases (gets more negative) as the charges get closer. - UU increases (gets less negative) as they get farther apart. - The force points toward decreasing UU, so toward each other.
Example: an electron near a proton has negative PE.

Graphs of U vs. r

2.1 - Electric Potential Energy
Both curves approach U=0U = 0 as r→∞r \to \infty. The slope tells you the force: Fr=−dUdrF_r = -\frac{dU}{dr}. For like charges the curve slopes down as rr grows, so Fr>0F_r > 0 (repulsive). For opposite charges the curve slopes up as rr grows, so Fr<0F_r < 0 (attractive). Both curves get steeper at small rr, which matches the force getting stronger as the charges get closer.

Key Principle: Force and Potential Energy

The electric force always points in the direction of decreasing potential energy.
This is a fundamental principle across all of physics:
F⃗=−dUdrr^\vec{F} = -\frac{dU}{dr}\hat{r}
  • When charges move with the force, the PE decreases.
  • When charges move against the force, the PE increases, which takes external work.

Summary Table: PE Behavior

Charge Combination
Sign of U
What the Charges Want
U when close
U when far
Same signs (++, −−)
Positive
To separate
Large +
Small + (→0)
Opposite signs (+−)
Negative
To attract
Large −
Small − (→0)
The universal rule: at infinite separation, U=0U = 0 for every charge pair. That’s the reference point.

Systems with Multiple Charges

For a system with several charges, the total electric potential energy is the sum of the potential energies of every unique pair.

The Principle of Superposition

Utotal=∑all pairsUij=∑all pairskqiqjrijU_{total} = \sum_{\text{all pairs}} U_{ij} = \sum_{\text{all pairs}} k\frac{q_iq_j}{r_{ij}}
Important: - Count each pair only once. The interaction between charges 1 and 2 is the same as between 2 and 1. - Include the signs of the charges, since the positive and negative terms add algebraically. - The distance rijr_{ij} is the separation between charges ii and jj.

Counting the Pairs

For nn charges, the number of unique pairs is:
Number of pairs=n(n−1)2\text{Number of pairs} = \frac{n(n-1)}{2}
  • 2 charges: 1 pair
  • 3 charges: 3 pairs
  • 4 charges: 6 pairs
  • 5 charges: 10 pairs

Example Problem: Three Charges in a Triangle

Problem: Derive an expression for the work required to assemble three charges into the configuration shown. They sit at the vertices of an equilateral triangle, with q1=−2Qq_1 = -2Q at the top, q2=−2Qq_2 = -2Q at the bottom left, and q3=+3Qq_3 = +3Q at the bottom right. Each side of the triangle has length dd.
2.1 - Electric Potential Energy

Solution

Step 1: Identify all the unique pairs
With 3 charges, there are 3 pairs: - Pair (1,2): q1q_1 and q2q_2 - Pair (1,3): q1q_1 and q3q_3 - Pair (2,3): q2q_2 and q3q_3
Step 2: Write the total potential energy
Utotal=U12+U13+U23U_{total} = U_{12} + U_{13} + U_{23}Utotal=kq1q2r12+kq1q3r13+kq2q3r23U_{total} = k\frac{q_1q_2}{r_{12}} + k\frac{q_1q_3}{r_{13}} + k\frac{q_2q_3}{r_{23}}
Step 3: Substitute the distances
All the sides have length dd:
Utotal=kq1q2d+kq1q3d+kq2q3dU_{total} = k\frac{q_1q_2}{d} + k\frac{q_1q_3}{d} + k\frac{q_2q_3}{d}
Step 4: Factor out the common terms
Utotal=kd(q1q2+q1q3+q2q3)U_{total} = \frac{k}{d}(q_1q_2 + q_1q_3 + q_2q_3)
Step 5: Substitute the charge values
With q1=−2Qq_1 = -2Q, q2=−2Qq_2 = -2Q, and q3=+3Qq_3 = +3Q:
Utotal=kd[(−2Q)(−2Q)+(−2Q)(+3Q)+(−2Q)(+3Q)]U_{total} = \frac{k}{d}[(-2Q)(-2Q) + (-2Q)(+3Q) + (-2Q)(+3Q)]Utotal=kd[4Q2−6Q2−6Q2]U_{total} = \frac{k}{d}[4Q^2 - 6Q^2 - 6Q^2]Utotal=kd[−8Q2]U_{total} = \frac{k}{d}[-8Q^2]Utotal=−8kQ2dU_{total} = -\frac{8kQ^2}{d}
Answer: the work required to assemble the configuration is
W=Utotal=−8kQ2dW = U_{total} = -\frac{8kQ^2}{d}
The read: the negative value means this is a bound system. Energy would be released during assembly, not required. The attractive interactions between the unlike charges beat out the repulsive one between the like charges.

Alternative Example: Four Charges in a Square

Problem: Four charges sit at the corners of a square with side length aa. Each has magnitude qq, arranged as: top-left (+), top-right (−), bottom-left (−), bottom-right (+). Find the total electric potential energy.
2.1 - Electric Potential Energy

Solution

Identify the 6 pairs and their distances.
Side interactions (distance = aa): 1. Top-left to top-right: (+q)(−q)(+q)(−q), so negative. 2. Top-right to bottom-right: (−q)(+q)(−q)(+q), so negative. 3. Bottom-right to bottom-left: (+q)(−q)(+q)(−q), so negative. 4. Bottom-left to top-left: (−q)(+q)(−q)(+q), so negative.
Diagonal interactions (distance = a2a\sqrt{2}): 5. Top-left to bottom-right: (+q)(+q)(+q)(+q), so positive. 6. Top-right to bottom-left: (−q)(−q)(−q)(−q), so positive.
Calculate the total PE:
Utotal=4⋅k(+q)(−q)a+2⋅k(+q)(+q)a2U_{total} = 4 \cdot k\frac{(+q)(−q)}{a} + 2 \cdot k\frac{(+q)(+q)}{a\sqrt{2}}Utotal=−4kq2a+2kq2a2U_{total} = -\frac{4kq^2}{a} + \frac{2kq^2}{a\sqrt{2}}Utotal=kq2a(−4+22)U_{total} = \frac{kq^2}{a}\left(-4 + \frac{2}{\sqrt{2}}\right)Utotal=kq2a(−4+2)U_{total} = \frac{kq^2}{a}\left(-4 + \sqrt{2}\right)Utotal≈kq2a(−2.59)U_{total} \approx \frac{kq^2}{a}(-2.59)
Answer: U=−kq2a(4−2)U = -\frac{kq^2}{a}(4 - \sqrt{2}), net negative, so it’s a bound system.

Example Problem: Three Charges on a Line

Problem: Three point charges sit on a line: q1=+2.0q_1 = +2.0 μC at x=0x = 0, q2=−3.0q_2 = -3.0 μC at x=0.20x = 0.20 m, and q3=+4.0q_3 = +4.0 μC at x=0.50x = 0.50 m. (a) Find the total electric potential energy of the system. (b) How much work would an external force have to do to pull all three charges infinitely far apart, starting and ending at rest?
2.1 - Electric Potential Energy

Solution

Step 1: List the pairs and their distances
With 3 charges, there are 3 pairs: - Pair (1,2): r12=0.20r_{12} = 0.20 m - Pair (1,3): r13=0.50r_{13} = 0.50 m - Pair (2,3): r23=0.30r_{23} = 0.30 m
Step 2: Find each pair’s potential energy, keeping the signs
U12=(9.0×109)(2.0×10−6)(−3.0×10−6)0.20=−0.27 JU_{12} = (9.0 \times 10^9)\frac{(2.0 \times 10^{-6})(-3.0 \times 10^{-6})}{0.20} = -0.27 \text{ J}U13=(9.0×109)(2.0×10−6)(4.0×10−6)0.50=+0.144 JU_{13} = (9.0 \times 10^9)\frac{(2.0 \times 10^{-6})(4.0 \times 10^{-6})}{0.50} = +0.144 \text{ J}U23=(9.0×109)(−3.0×10−6)(4.0×10−6)0.30=−0.36 JU_{23} = (9.0 \times 10^9)\frac{(-3.0 \times 10^{-6})(4.0 \times 10^{-6})}{0.30} = -0.36 \text{ J}
Step 3: Add them as scalars
Utotal=−0.27+0.144−0.36=−0.49 JU_{total} = -0.27 + 0.144 - 0.36 = -0.49 \text{ J}
Answer: (a) Utotal=−0.49U_{total} = -0.49 J. (b) Pulling them apart takes the system from U=−0.49U = -0.49 J to U=0U = 0, so the external force does W=ΔU=0−(−0.49 J)=+0.49W = \Delta U = 0 - (-0.49 \text{ J}) = +0.49 J. The system is bound: you have to put energy in to take it apart.

The Connection to Work

The work-energy theorem applies:
Wexternal=ΔU=Ufinal−UinitialW_{external} = \Delta U = U_{final} - U_{initial}
When you assemble charges starting from infinity: - Uinitial=0U_{initial} = 0, since all the charges are infinitely far apart. - UfinalU_{final} is the configuration energy. - So W=UfinalW = U_{final}.
What the sign means: - Positive work: you have to do work to assemble it, because the charges resist coming together. - Negative work: the system releases energy as it assembles, because the charges want to come together.

Key Concepts Summary

  1. PE is a scalar. Add algebraically, not vectorially, unlike forces and fields.
  1. Signs matter. The product of the charges sets the sign:
      • (+)(+)=+(+)(+) = +, so positive PE.
      • (−)(−)=+(−)(−) = +, so positive PE.
      • (+)(−)=−(+)(−) = −, so negative PE.
  1. Zero reference at infinity. U=0U = 0 when the charges are infinitely far apart.
  1. Conservative force. The path doesn’t matter, only the initial and final positions.
  1. Superposition. The total PE is the algebraic sum of all the pair interactions.

Common Mistakes

  1. Counting pairs twice. Each pair interaction gets counted exactly once. Don’t double-count the interaction between charges 1 and 2.
  1. Forgetting the signs of the charges. The formula includes each charge’s sign. A positive and a negative charge give negative PE, not positive.
  1. Confusing PE with force. High PE doesn’t mean high force. PE tells you about the energy stored in the configuration, while force tells you which way the charges will move.
  1. Using the wrong reference point. Always use infinity as the zero-PE reference, not the positions shown in the problem, unless the problem says otherwise.
  1. Missing the diagonal interactions. In 2D and 3D configurations (squares, cubes, and so on), the charges interact across the diagonals too, not just along the edges.

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